Composite Solid Electrolyte Na2SO4–Al2O3

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The effect of adding nanosized γ-Al2O3 on the properties and structure of Na2SO4 was studied using differential scanning calorimetry, vibrational spectroscopy, electrochemical impedance spectroscopy and X-ray diffractometry. It was shown that the introduction of nanosized γ-Al2O3 into sodium sulfate leads to a significant increase in the specific ionic conductivity to 8.48 × 10–5 S/cm at a temperature of 603 K. The results of X-ray diffraction studies and vibrational spectroscopy confirm partial amorphization of the salt in the near-surface region of nanoparticles. The data obtained indicate that the sodium sulfate-based composite can be a promising ionic conductor for solid-state Na-ion batteries in the temperature range of 513–603 K.

作者简介

K. Rabadanova

Analytical Center for Collective Use, Institute of Physics, DFRC RAS

Email: rksh83@mail.ru
Makhachkala, Russia

M. Gafurova

Analytical Center for Collective Use, Institute of Physics, DFRC RAS

Email: malik52@mail.ru
Makhachkala, Russia

A. Amirova

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: muhamadahmedov@mail.ru
Chernogolovka, Russia

D. Kovalev

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: rksh83@mail.ru
Chernogolovka, Russia

M. Akhmedova

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: rksh83@mail.ru
Chernogolovka, Russia

M. Kakagasanova

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: rksh83@mail.ru
Chernogolovka, Russia

M. Ataeva

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: rksh83@mail.ru
Chernogolovka, Russia

Z. Kubataeva

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

Email: rksh83@mail.ru
Chernogolovka, Russia

M. Kadieva

A.G. Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: rksh83@mail.ru
Chernogolovka, Russia

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