SINGLE-ATOM ALLOY Pd1Ag6/Al2O3 EGG-SHELL CATALYST FOR SELECTIVE ACETYLENE HYDROGENATION

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Abstract

In this work, a single-atom alloy Pd1Ag6/Al2O3 catalyst for the selective hydrogenation of acetylene was obtained with an egg-shell distribution of the active phase over the catalyst granules. The formation of an egg-shell structure was confirmed by electron probe microanalysis. It was found that metals are predominantly localized at a depth of 130–160 µm from the surface of the granules. Transmission electron microscopy and X-ray photoelectron spectroscopy have revealed the formation of a substitutional PdAg solid solution with electron density transfer from Ag to Pd. The formation of Pd1 single sites was confirmed by FTIR spectro-scopy of adsorbed CO. In the selective hydrogenation of acetylene the synthesized single-atom alloy Pd1Ag6/Al2O3 with egg-shell distribution showed high selectivity, which radically exceeds the selectivity of the palladium counterpart.

About the authors

I. S. Mashkovsky

Zelinsky Institute of Organic Chemistry RAS

Author for correspondence.
Email: im@ioc.ac.ru
Russian Federation, 119991, Moscow

D. P. Melnikov

Zelinsky Institute of Organic Chemistry RAS; Gubkin University

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow; Russian Federation, 119991, Moscow

P. V. Markov

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

G. N. Baeva

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

N. S. Smirnova

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

G. O. Bragina

Zelinsky Institute of Organic Chemistry RAS

Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

A. Yu. Stakheev

Zelinsky Institute of Organic Chemistry RAS

Author for correspondence.
Email: st@ioc.ac.ru
Russian Federation, 119991, Moscow

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Copyright (c) 2023 И.С. Машковский, Д.П. Мельников, П.В. Марков, Г.Н. Баева, Н.С. Смирнова, Г.О. Брагина, А.Ю. Стахеев