Dielectric Properties of Graphite Oxide Polymeric Composites Based on N-Vinylpirrolidone Copolymers with Different Topologies

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Resumo

The dielectric properties of graphite oxide composite materials based on a biocompatible branched copolymer of N-vinylpyrrolidone with 1,6-hexanediol dimethacrylate and a cross-linked copolymer of N‑vinylpyrrolidone with triethylene glycol dimethacrylate are studied. High-frequency (9.8 GHz) and low-frequency (25 Hz–1 MHz) measurements of the complex permittivity and electrical conductivity of polymer composites are carried out and their dependences on the polymer matrix topology and formation conditions are analyzed. Copolymers and composites based on them are characterized by IR, UV, and visible spectroscopy, dynamic light scattering, and the surface morphology of nanocomposite polymer matrices is characterized by optical microscopy. It is shown that the proposed electrophysical approach makes it possible to additionally characterize polymer matrices with carbon nanofillers.

Sobre autores

G. Simbirtseva

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: sgvural@mail.ru
142432, Chernogolovka, Russia

C. Babenko

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: sgvural@mail.ru
142432, Chernogolovka, Russia

E. Perepelitsina

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: sgvural@mail.ru
142432, Chernogolovka, Russia

P. Komendant

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Email: sgvural@mail.ru
142432, Chernogolovka, Russia

S. Kurmaz

Institute of Problems of Chemical Physics, Russian Academy of Sciences

Autor responsável pela correspondência
Email: sgvural@mail.ru
142432, Chernogolovka, Russia

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Declaração de direitos autorais © Г.В. Симбирцева, С.Д. Бабенко, Е.О. Перепелицина, Р.И. Комендант, С.В. Курмаз, 2023