SULFIDE SULFUR ISOTOPE SOURCES OF THE NEOARCHEAN IRON ORE DEPOSITS IN THE KOSTOMUKSHA GREENSTONE BELT, KARELIA (RUSSIA)

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

In this paper we provide primary data on multi-isotope sulfur composition of the Neoarchean BIF sulfides of the Kostomuksha greenstone belt in Karelia (the Karelian Craton on Fennoscandian Shield). These sulfides formed at 2760–2740 Ma. Pyrite associated with fine-grained magnetite showed negative δ34S values (up to –7.8‰) and positive Δ33S values (up to +0.7‰). At the same time, pyrrhotite of vein-disseminated ores associated with shale demonstrated both negative δ34S (up to –6‰), and Δ33S values (up to –0.46‰). Based on the obtained data we assume that sulfur for the BIF sulfides was transported from three reservoirs: - atmospheric (photolytic), hydrospheric (seawater sulfate), and magmatogenic. Sulfur isotope ratios in sulfides preserved the evidence of interaction between abiological (atmospheric, hydrothermal) and biological processes (dissimilatory microbial reduction) that occurred during the formation of iron ore deposits of the Kostomuksha greenstone belt in Karelia.

About the authors

S. V. Vysotskiy

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Author for correspondence.
Email: svys@mail.ru
Russian Federation, Vladivostok

A. I. Khanchuk

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: svys@mail.ru
Russian Federation, Vladivostok

T. A. Velivetskaya

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: svys@mail.ru
Russian Federation, Vladivostok

A. V. Ignatiev

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: svys@mail.ru
Russian Federation, Vladivostok

A. V. Aseeva

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: svys@mail.ru
Russian Federation, Vladivostok

N. S. Nesterova

Far East Geological Institute, Far Eastern Branch of the Russian Academy of Sciences

Email: svys@mail.ru
Russian Federation, Vladivostok

References

  1. Bekker A., Slack J.F., Planavsky N., Krapež B., Hofmann A., Konhauser K.O., Rouxel O.J. Iron formation: the sedimentary product of a complex interplay among mantle, tectonic, oceanic, and biospheric processes // Economic Geology. 2010. V. 105. P. 467–508.
  2. Konhauser K.O., Planavsky N.J., Hardisty D.S., Rob-bins L.J., Warchola T.J., Haugaard R., Lalonde S.V., Partin C.A., Oonk P.B.H., Tsikos H., Lyons T.W., Bekker A., Johnson C.M. Iron formations: A global record of Neoarchaean to Palaeoproterozoic environmental history // Earth- Science Reviews 2017. V. 172. P. 140–177.
  3. Литовченко Н.И. К проблеме происхождения железистых кварцитов // Отечественная геология. 2001. № 6. С. 70–76.
  4. Dreher, C.L. Schad M., Robbins L.J., Konhauser K.O., Kappler A., Joshi P. Microbial processes during deposition and diagenesis of Banded Iron Formations // Paläontologishe Zeitschrift. 2021. V. 95. 593–610.
  5. Кузнецов В.Г. Геохимические обстановки седиментации докембрия. // Литология и полезные ископаемые. 2020. № 2. С. 117–130.
  6. Li W., Beard B.L., Johnson C.M. Biologically recycled continental iron is a major component in banded iron formations // PNAS. 2015. V. 112 (27) P. 8193–8198.
  7. Alfimova N., Raza Mohd Baqar, Felitsyn S., Matrenichev V., Bogomolov E., Nasipuri P., Saha L., Pati J.K., Kumar V. Isotopic Sm-Nd signatures of Precambrian Banded Iron Formation from the Fennoscandian shield, East-European Platform, and Bundelkhand craton, India // Precambrian Research. 2019. V. 328. P. 1–8.
  8. Слабунов А.И., Нестерова Н.С., Егоров А.В., Кулешевич Л.В., Кевлич В.И. Геохимия, геохронология цирконов и возраст архейской железорудной толщи Костомукшского зеленокаменного пояса Карельского кратона Фенноскандинавского Щита // Геохимия. 2021. Т. 66. № 4. С. 291–307.
  9. Слабунов А.И., Светов С.А., Степанова А.В., Медведев П.В., Полин А.К. Новая тектоническая карта Карелии: принципы построения и их реализация // Труды Карельского научного центра РАН. 2022. № 5. С. 132–138.
  10. Trendall A.F., Compston W., Nelson D.R., de Laeter J.R., Bennett V.C. SHRIMP zircon ages constraining the depositional chronology of the Hamersley Group, Western Australia // Australian Journal of Earth Sciences. V. 51. № 5. P. 621–644.
  11. Ignatiev A.V., Velivetskaya T.A., Budnitskiy S.Y., Yakovenko V.V., Vysotskiy S.V., Levitskii V.I. Precision analysis of multisulfur isotopes in sulfides by femtosecond laser ablation GC-IRMS at high spatial resolution // Chemical Geology. V. 493. 316−326.
  12. Ono S., Beukes N.J., Rumble D. Origin of two distinct multiple-sulfur isotope compositions of pyrite in the 2.5 Ga Klein Naute Formation, Griqualand West Basin, South Africa // Precambrian Research. 2009. V. 169. № 1–4. P. 48–57.
  13. Костомукшский рудный район (геология, глубинное строение и минерагения). Отв. ред. Горько-вец В.Я., Шаров Н.В. Петрозаводск. 2015. 322 с.
  14. Rickard D., Luther G.W. Chemistry of iron sulfides // Chemical Reviews, 2007. V. 107. P. 514–562.
  15. Rickard D. Sulfidic sediments and sedimentary rocks. Amsterdam: Newnes. 2012. P. 1–801.
  16. Guy B.M., Ono S., Gutzmer J., Kaufman A.J., Lin Y., Fogel M.L., Beukes N.J. A multiple sulfur and organic carbon isotope record from non-conglomeratic sedimentary rocks of the Mesoarchean Witwatersrand Supergroup, South Africa // Precambrian Research. 2012. V. 216– 219. P. 208–231.
  17. Philippot P., Van Zuilen M., Lepot K., Thomazo C., Farquhar J., Van Kranendonk M. J. Early Archaean microorganisms preferred elemental sulfur, not sulfate // Science. 2007. V. 317. P. 1534–1537.
  18. Vysotskiy S.V., Velivetskaya T.A., Ignatiev A.V., Slabu-nov A.I., Aseeva A.V. Multiple Sulfur Isotope Evidence for Bacterial Sulfate Reduction and Sulfate Disproportionation Operated in Mesoarchaean Rocks of the Karelian Craton // Minerals. 2022. V. 12. P. 1143. https://doi.org/10.3390/min12091143
  19. Kuleshevich L.V., Gor’kovets V.Ya. Mineralogy of the Precambrian Southern Kostomuksha Gold Prospect in Karelia // Geology of Ore Deposits. 2008. V. 50. № 7. P. 599–608.

Supplementary files

Supplementary Files
Action
1. JATS XML
2.

Download (986KB)
3.

Download (86KB)
4.

Download (2MB)

Copyright (c) 2023 С.В. Высоцкий, А.И. Ханчук, Т.А. Веливецкая, А.В. Игнатьев, А.В. Асеева, Н.С. Нестерова