First Assessment of Soil Cover Pollution with Polycyclic Aromatic Hydrocarbons in Ulan-Ude

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Abstract

For the first time, the content of 17 individual PAHs was analyzed in samples of background and urban soils obtained during a geochemical survey of the territory of Ulan-Ude in the summer of 2022. The average content of PAHs in the urban soils is 801 ng/g, which is more than 8.5 times higher than the level in background chestnut soils. The soil cover is contaminated predominantly with mediumand highmolecular-weight polyarenes. The share of individual PAHs in the soils of Ulan-Ude ranges within 4–11% with an average value of 6%. In the urban soil cover, ten high-contrast anomalies were identified with the amount of PAHs ranging from 3162 to 10189 ng/g. The principal component analysis and indicator ratios of polyarenes made it possible to identify the main types of sources and their contribution to urban soil pollution.

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About the authors

N. E. Kosheleva

Lomonosov Moscow State University

Email: niyaz.zh@mail.ru
Russian Federation, Moscow

N. B. Zhaksylykov

Lomonosov Moscow State University

Author for correspondence.
Email: niyaz.zh@mail.ru
Russian Federation, Moscow

Yu. A. Zavgorodnyaya

Lomonosov Moscow State University

Email: niyaz.zh@mail.ru
Russian Federation, Moscow

N. S. Kasimov

Lomonosov Moscow State University

Email: niyaz.zh@mail.ru

Academician of the RAS

Russian Federation, Moscow

References

  1. Касимов Н. С., Власов Д. В., Кошелева Н. Е., Никифорова Е. М. Геохимия ландшафтов Восточной Москвы. М.: АПР, 2016. 276 с.
  2. Ровинский Ф. Я. Теплицкая Т. А., Алексеева Т. А. Фоновый мониторинг полициклических ароматических углеводородов. Л.: Гидрометеоиздат, 1988. 224 с.
  3. Alegbeleye O. O., Opeolu B. O., Jackson V. A. Polycyclic Aromatic Hydrocarbons: A Critical Review of Environmental Occurrence and Bioremediation // Environmental Management. 2017. V. 60. № 4. P. 758–783. https://doi.org/10.1007/s00267-017-0896-2
  4. Gusev A., Batrakova N. Assessment of PAH pollution levels, key sources and trends: contribution to analysis of the effectiveness of the POPs Protocol. Technical Report 2/2020. June 2020. Meteorological Synthesizing Centre – East, Moscow, Russia. 52 p.
  5. Геохимия полициклических ароматических углеводородов в горных породах и почвах. Геннадиев А. Н., Пиковский Ю. И. (ред.). М.: Изд-во Моск. ун-та, 1996. 192 с.
  6. Dat N.-D., Chang M. B. Review on characteristics of PAHs in atmosphere, anthropogenic sources and control technologies // Science of the Total Environment. 2017. V. 609. P. 682–693.
  7. Халиков И. С., Яхрюшин В. Н., Корунов А. О. Концентрация 4–6 ядерных ароматических углеводородов в атмосферном воздухе городов России в зимнее время // Экологическая химия. 2021. Т. 30. № 2. С. 59–70.
  8. Битюкова В. Р., Дехнич В. С., Кравчик А. И., Касимов Н. С. Оценка влияния автономных систем отопления жилых строений на загрязнение воздуха в муниципальных образованиях (на примере Байкальского региона) // Вестник Московского университета. Серия 5: География. 2024. Т. 79. № 1. С. 22–36. https://doi.org/10.55959/MSU0579-9414.5.79.1.2
  9. Хаустов А. П., Редина М. М. Индикаторные соотношения концентраций полициклических ароматических углеводородов в объектах сжигания угольного топлива и биомассы // Антропогенная трансформация природной среды. 2019. № 5. С. 64–71.
  10. Devos O., Combet E., Tassel P., Paturel L. Exhaust emissions of PAHs of passenger cars // Polycyclic Aromatic Compounds. 2006. V. 26. P. 69–78. https://doi.org/10.1080/10406630500519346
  11. Miguel A. H., Kirchstetter T. W., Harley R. A., Hering S. V. On-road emissions of particulate polycyclic aromatic hydrocarbons and black carbon from gasoline and diesel vehicles // Environmental Science and Technology. 1998. V. 32. № 4. P. 450–455. https://doi.org/10.1021/es970566w
  12. Mętrak M., Chmielewska M., Sudnik-Wójcikowska B., Wiłkomirski B., Staszewski T., Suska-Malawska M. Does the railway function of railway infrastructure determine qualitative and quantitative composition of contaminants (PAHs, heavy metals) in soil and plant biomass? // Water, Air and Soil Pollution. 2015. V. 226. № 8. P. 253–265. https://doi.org/10.1007/s11270-015-2516-1
  13. Журавлева Е. В., Михайлова Е. С., Журавлева Н. В., Исмагилов З. Р. Полициклические ароматические углеводороды из углей в объектах окружающей среды // Химия в интересах устойчивого развития. 2020. Т. 28. № 3. С. 328–337. https://doi.org/10.15372/KhUR2020237
  14. Кошелева Н. Е., Никифорова Е. М., Тимофеев И. В., Завгородняя Ю. А. Полициклические ароматические углеводороды в почвах Северобайкальска // География и природные ресурсы. 2023. № 4. С. 77–89. https://doi.org/10.15372/GIPR20230408
  15. Константинова Е. Ю., Сушкова С. Н., Мин кина Т. М., Антоненко Е. М., Константинов А. О., Хоро ша вин В. Ю. Полициклические ароматические углеводороды в почвах промышленных и селитебных зон Тюмени // Известия Томского политех. университета. Инжиниринг георесурсов. 2018. Т. 329. № 8. С. 66–79.
  16. Kosheleva N. E., Nikiforova E. M., Zhaxylykov N. B. Ecological and geochemical assessment of the state of soils in the city of Baikal’sk according to the content of polycyclic aromatic hydrocarbons // Eurasian Soil Science. 2024. V. 57. № 4. P. 692–709.
  17. Song N., Ma J., Yu Y., Yang Z., Li Y. New observations on PAH pollution in old heavy industry cities in northeastern China // Environmental Pollution. 2015. V. 205. P. 415–423. https://doi.org/10.1016/j.envpol.2015.07.005
  18. Xu Z., Wang C., Li H., Xu S., Du J., Chen Y., Ma C., Tang J. Concentration, distribution, source apportionment, and risk assessment of surrounding soil PAHs in industrial and rural areas: a comparative study // Ecol. Indic. 2021. V. 125. 107513. https://doi.org/10.1016/j.ecolind.2021.107513
  19. Yunker M. B., Macdonald R. W., Vingarzan R., Mitchell R. H., Goyette D., Sylvestre S. PAHs in the Fraser River Basin: a critical appraisal of PAH ratios as indicators of PAH source and composition // Org. Geochem. 2002. V. 33. P. 489–515. https://doi.org/10.1016/S0146-6380(02)00002-5
  20. Stogiannidis E., Laane R. Source characterization of polycyclic aromatic hydrocarbons by using their molecular indices: An overview of possibilities // Rev. Environ. Contaminat. Toxicol. 2015. V. 234. P. 49–133. https://doi.org/10.1007/978-3-319-10638-0_2

Supplementary files

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2. Fig. 1. Composition of PAHs in background soils and in Ulan-Ude soils

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3. Fig. 2. Soil sampling points in functional zones (top right) and distribution of PAH sum in the upper (0-10 cm) soil layer of Ulan-Ude city (numbers indicate local anomalies of PAHs)

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