Synthesis of substituted 2-arylimino-3-oxopropanenitriles and 2-(arylimino)propanedinitriles by oxidative coupling of primary aromatic amines with aroylacetonitriles and malononitrile

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详细

Aromatic amines enter into an oxidative coupling reaction with 3-aryl-3-oxopropanenitriles in the presence of selenium(IV) oxide to form the corresponding 2-arylimino-3-oxopropanenitriles. In the case of a similar reaction of arylamines with malononitrile, 2-aryliminopropanedinitritles are formed.

作者简介

A. Kachanov

Far-Eastern Federal University

Email: kachanov.av@dvfu.ru
Universitetskii pr., L901, Russky Island, Vladivostok, 690922 Russia

M. Kucheshov

Far-Eastern Federal University

Universitetskii pr., L901, Russky Island, Vladivostok, 690922 Russia

O. Slabko

Far-Eastern Federal University

Universitetskii pr., L901, Russky Island, Vladivostok, 690922 Russia

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